Gorgeous blouse, excellent jeans! For maxi skirts, I'd probably suggest you look for something straighter/less A-line, and in a less heavy fabric - but it's a fun experiment.
I'll echo those who don't care much for the PB phrase. Adding kitty-cat connotations makes it worse in my view - we aren't dressed-up pets! I will call those "bow blouses" also. (Which I don't think yours is...narrow ties, IMO, come across quite differently from the wide ribbony ones I associate with the old Dress For Success look.)
As for tie-front blouses, I have some with string ties; they have a kind of poet-shirt/bohemienne/gypsy feel, and I think they look good on me. However, anything with a big foofy bow in the front I will avoid. Anything that can be interpreted as frou-frou, cutesy, or little-girlish is right out.
(Oh BTW...DH calls his underwear "manties." It's kind of adorable!)