I use Twice because even though they don't pay much ( $3-4 an item, though I can't always tell if something went for more, haven't figured out the website completely and not sure I want to drill down that far even if I could), it is painless. Tape up a box, label, drop off. Cash check. Don't think about it (the cost differential) . It became even more appealing when they started taking purses and shoes.
I still donate lots of items to church and Goodwill, but I do target my "accepted name brands" for Twice. Somehow that has turned out to be the right approach for me right now. If I were more involved with a specific women-to-work charity or service, I would funnel things there--that' s also something I might like to do in my "next chapter".