It depends on how much you like your shoes to blend in with the rest of your outfit. Given you have brown hair, I think these will work for you.
My colouring is different to yours (light blonde hair) and so I have found it tricky with the dark brown cool toned boots I own (in Finds), which I thought I would wear with everything, but in reality, I only wear them with dark denim. My boots are less refined than yours, so that may be part of the issue. I find if I am going to wear a dark boot, I default to either black or navy.