I don't have a medical condition as such, but I already suffer from excessive sweating & running too hot (as in I'll be wearing one layer & sandals in HK whereas others are literally wearing puffer coats next to me, lol!)
You've got some great suggestions here already - I agree that viscose/ rayon is not always made equal, but Zara has some great printed shirt dresses that hide sweat/ are breathable & look polished enough for work (with belts & pockets!) My attached one is called the 'Marilyn' - think they have it in sky blue too.
Further to @SF's comment about Intimissimi, they do some great thinner tops in smoother fabrics too (look for the ones blended with modal - still breathable but looks professional enough to show at work, rather than the ribbed versions).
I also like sleeveless toppers that don't add any warmth (but I wear them over the top to hide sweat stains (TMI i know) in a pinch).
Lastly, I actually bring a second change of clothes with me on long teaching days (especially if I'm going to a new government facility where I need to look polished) - I bring two tops in similar colours (so people can't see the difference so easily) with a change of underwear (also TMI sorry, but you asked haha!)
Other quick tips I employ are: an extra claw clip (to stick my hair up on public transport), collarless tops, a change of (no-show) socks, a convertible bag (even straps can get hot when they're holding your clothing in place), & looser fits (I'll tuck in my blouse/ roll down my sleeves & trousers once I get to work)
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