What a great question you raise!
Like Angie, I find I have more concerns matching the metals in my outfit rather than matching a certain metal with a certain color. For example, I have a Marciano leather jacket I adore, but all the buttons and zippers are yellow gold; So I won't pair it with certain purses adorned with silvery metals, nor with belts with silver buckles. I am all for mixing metals in my jewelry, but from an accessory to another, it just looks like I didn't pay attention.
About the cognac shoes: they are wonderfully chic. What a great pair of footwear you got there! I bet they will be most useful. I have found this particular shade of brown a bit trickier to pair with any color, and am still learning. Contrary to others, I do not find it to be as neutral as black or navy. Despite this, I adore its rich tone, its authentic feel. Here is the fruit of my trials:
1) I have found cognac looks stunning with navy and cream and gold, as inspired by the Hermes scarf below (think English Old money horse riding preppy);
2) It gives surprising depth to black, creating an interest. I would certainly try your new shoes with an all black outfit and a couple of other wooden or cognac or brown accessories. I would even go as far as trying them with black tights, (even if they are peep toed, so the tight must be seamless) for a very avant-garde effect.
3) It looks very fresh and young, in a vague "Laura Ashley" way, with blush. Maybe it is because the combination is reminiscent of certain small flower prints. Salmon pinks works well too.
4) It looks good with grey too.
5) Oh, and of course, any denim.
6) Oh, and white too! Even better: with white denim!
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