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I've heard many times from Clinton and Stacy to not wear polyester especially 100% poly. Yet, I see 100% poly items and I'm not sure if they're a no-no due to the fabric.
I personally seriously dislike how it feels on my skin so I do not wear it all. However, companies like BCBG make some really gorgeous dresses made of polyester matte jersey so I might make an exception for that.
I own a wrap shirt from target that is supercomfy and hugs my curves in all the right ways, but by half way through the day I feel seriously sweaty and gross. So I don't wear it much at all.