the gals have you covered already with the graphic tee idea! layering with a biker jacket or denim jacket is great too! accessories can also have an impact on an outfit...
for shoes, i think ballet flats or flat boots would look nice, depending on the weather. don't forget the power of tights with boots!
a fun chunky necklace, bangles, or funky earrings can make it a little more carefree and less corporate. you could also try adding a belt- depending on the style of it, it can make the outfit a little more casual.
and finally, scarves can make an outfit more casual too, depending on the material. i'd steer away from silk scarves for a casual look.
ok, let's see some outfits now! :)